When oxygen is absent, sulfatereducing bacteria are active and produce hydrogen sulfide causing sulfide stress cracking. Effect of testing temperature on sulfide stress cracking. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking.
Sulfide stress cracking of pipelinecase history onepetro. Sulfide stress corrosion cracking ssc is a form of hydrogen embrittlement cracking which occurs when a susceptible material is exposed to a corrosive environment containing water and h2s at a critical level of applied or residual tensile stress. This part of ansinace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stress oriented hydrogeninduced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. The results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking. Reliability of dissimilar metal welds subjected to sulfide. Since the first discovery of stress corrosion cracking scc on the exterior surface of a buried high. Other types of material damage include hydrogen blistering, hydrogeninduced cracking hic, and stressoriented hydrogeninduced cracking sohic, which are. Sulfide stress cracking how is sulfide stress cracking. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. Among the most prone to sulfide stress cracking include valve trim, blowout preventer hard parts and tool joints. Sulfide stress cracking an overview sciencedirect topics. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour.
Tcr engineering mumbai corrosion testing, nace, astm. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Pdf sulfide stress corrosion cracking and hydrogen. Sulfide stress cracking ssc is just one of several forms of hydrogen. The susceptibility to sscc depends on the microstructural characteristics of the material. Standard test method laboratory testing of metals for. Sulfide stress cracking of stainless steel 410 in sour. Sulfide stress corrosion cracking of steels corrosion. Specialized stress corrosion cracking testing capabilities. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Resistance to sulfide stress cracking natural gas and oil inherently contain a certain amount of hydrogen sulphide h 2 s. Abstract it has been found that higher yield strength stainless steel 410 is generally more susceptible to sulfide stress cracking, but complicating factor such as microstructure can have significant effect in this susceptibility too. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking.
Steel castings handbook supplement 8 high alloy data. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of. Micro alloyed pipeline steels are commonly used in the petroleum industry for transport applications 1. It is appreciated that a material used in an h2s corrosive medium can suffer sulfide stress cracking ssc, a form of hydrogen embrittlement cracking occurring in h2s environments. Coilgard inhibitor protects against cracking corrosion that can cause catastrophic failures in stressed steels, such as coiled tubing.
Sulfide stress corrosion cracking sscc in crude oil field environment including hydrogen sulfide h 2 s has been recognized as a materials failure mechanism. Ian sutton, in plant design and operations second edition, 2017. Oct 24, 20 sulfide stress cracking resistant drill pipe addresses h2s challenges. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Coilgard inhibitor can be applied as a batch treatment or by placement in the treating fluid. The article also introduces a quantitative criterion to determine the maximum allowable defect size based on fracture mechanics principles. Wet hydrogen sulfide h2s cracking inspectioneering. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Typically these conditions occur in oil and gas extraction, predominantly offshore. When oxygen is present, some bacteria may directly oxidize iron to iron oxides and hydroxides. Processes or conditions involving wet hydrogen sulfide, i.
Nace standard tm0177, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments 1. Stress corrosion cracking tests using doublecantilever. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Pdf stress corrosion cracking and hydrogen cracking. Ansinace mr0175iso 15156, petroleum and natural gas industries. Hydrogen sulphide corrosion cracking of steel corrosion. Pdf the wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of. H 2 s can cause sulfide stress cracking of stainless steels. Investigators, after discarding embrittlement as a. Sulfide stress cracking nace mr01752002, mr0175iso 15156.
Microbial corrosion, commonly referred to as microbiologically influenced corrosion mic is caused by microorganisms. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking. It looks at the various forms of cracking, the nature of cracking, its causes and how it is prevented. Induced cracking and sulfide stress cracking uhlig. Corrosionpedia what is sulfide stress cracking ssc. Both references 1 and 2 underline the detrimental e.
But, the presence of h 2 s in well fluids imposes severe restrictions on the use of tubular goods due to sulfide stress cracking phenomenon 2. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body. Sour service is a environment containing water and h2s hydrogen sulfide with pressure of 50ppm if the presence of hydrogen sulfide i. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Usually, the resistance to ssc is evaluated using nace standard tm01771, and in particular the tensile test method a. Sulfide stress cracking ssc has been regarded as a source of major failures in the oil and gas industry, causing significant economic and human losses. Sulfide stress cracking ssc was first identified and the mechanism outlined in the 1940s after several failures of oil and gas systems in texas and canada. The laboratory critical constants were found to be lower. Foreword this standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s.
In this chapter the terms eac and scc are generally interchangeable. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. Stress corrosion cracking tests using doublecantileverbeam specimens ajit roy october 25,1996 this is an informal report intended primarily for internal or limited external. Standard material requirements sulfide stress cracking. Sulfide stress crackingresistant drill pipe addresses h2s.
The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi. Standard material requirements materials resistant to. Types of corrosion american galvanizers association. Nanostructured steel susceptibility to sulfide stress cracking. A95 stainless steel is designed to combine improved resistance to stress corrosion cracking including sulfide stress corrosion crackingpitting, crevice corrosion and high strength when compared with other stainless alloys.
Hydrogen assisted cracking of high strength alloys richard. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Sulfide stress cracking and corrosion fatigue of steels. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Highstrength steels with improved sulfide stress cracking resistance. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches.
Materials for use in h2scontaining environments in oil and gas production 1. Stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Scavenging of h 2s is not necessary for it to function.
Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Mar 27, 2014 the valve body alloy was a216wcc cast carbon steel. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. The influence of microstructure and inclusion on the susceptibility to stress oriented hydrogen induced cracking, sohic, or type i sulfide stress cracking, ssc, was investigated for two kinds of. Dec 19, 2019 ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres. Crolet points out that the combination of stress and hydrogen initiates the formation of local hic and then the formation of sohic.
A lower carbon content, as in grade ca6nm class b, permits heat treating to a lower maximum hardness and str ength whci h results in improved corrosion resistance, particularly resistance to sulfide stress corrosion cracking. What is the abbreviation for sulfide stress cracking. Sulfide stress cracking resistance of 95 and 110 ksi octg sour. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hydrogen assisted cracking of high strength alloys richard p. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Sulfide stress cracking mostly occurs in very highly acidic environments. Which alloy is best to resist sulfide stress cracking and stress corrosion cracking. Mar 28, 2011 weishan huang, jingli luo, hani henein and josiah jordan, sulfide stress cracking assessment of lowalloy l80 casing steel in h 2 s environment, anticorrosion methods and materials, 10. Is sulfide stress cracking an anodic or a cathodic process. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide.
It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Summary sulfide stress cracking ssc is just one of several forms of hydrogen. Test frames for applying cyclic loads with the measurement of crack propagation rates. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s.
Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. Concentration cells can form in the deposits of corrosion products, leading to localized corrosion. Ssc abbreviation stands for sulfide stress cracking. Hydrogen sulfide stress corrosion cracking in materials for.
The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. Sulfide stress cracking ssc ssc is a form of hydrogen stress cracking hsc. It is an environmental cracking mechanism that can initiate on the surface of high strength alloy steels or carbon steels containing localized areas of high hardness stress. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. It is also interesting to remark that nace standard mr 0103, materials resistant to sulfide stress cracking in corrosive petroleum refining environments ansinace, 2012, which was adapted from iso 15156 to cover sour petroleum refining and related processing environments containing h 2 s, does not impose any restriction in terms of nickel content.
Technical report development for material and application. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Welding residual stress generation and metallurgical change by fusion welding process increase the cracking driving force and reduce the resistance of brittle fracture as well as environmental fracture. Sulfide stress cracking oil and gas pipelines wiley. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. The high resistance of sandvik saf 2205 is shown in the figure by the fact that very high stresses, about 1. Uniform and non uniform thinning of pipe walls due to metal removal corrosion was controlled by the development of. Dec 21, 2017 in other words, it can support a stress of 80,000 psi with an elongation of less than 0. Home which alloy is best to resist sulfide stress cracking and stress. Sulfide stress cracking oil and gas pipelines wiley online library.
After several sulfide stresscracking failures occurred in texas in the mid1970s. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. In this study, effects of environmental temperature on susceptibility to sulfide stress cracking ssca type of hydrogen embrittlement he occurring in sour environmentsof low alloy steels were investigated from the perspective of hydrogen entry, absorption, and accumulation. February 19, 2017 by mariano iannuzzi in a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. During investigation many cracks were observed on the inner surface of the valve body grown from the surface pits. Stress corrosion crack scc is a crack which may be intergranular or transgranular depending on the material, resulting from the combined action of corrosion and stress, either external applied or internal residual. The opinions and conclusions stated are those of the author and may or may not be those of the laboratory. Stress corrosion cracking can be defined as the interaction of a tensile stress and an aqueous environment acting on a susceptible metallic surface to initiate and propagate cracks. Which alloy is for sulfide stress and stress corrosion cracking. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular. This type of cracking is also known as underbead cracking, toe cracking, or delayed cracking. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Pdf a discussion covers the nace international standard mr0175. Pdf sulfide stress corrosion cracking and hydrogen induced.
The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. This part of iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stress oriented hydrogeninduced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. In combination with increased temperatures and pressure in environments containing chloride, sulfide stress cracking ssc can occur. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Pdf detecting sulfide stress cracking and applying nace mr0175. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress cracking of nickelcontaining lowalloy. Laboratory testing of metals for resistance to sulfide stress. This article describes current industry practices to catalog features observed after sulfide stress cracking testing. Sulfide stress cracking nace mr01752002, mr0175iso. Stressoriented hydrogeninduced cracking of l360qs steel.
Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Nace standard tm01772005 laboratory testing of metals. The limit of sour service ss grades regarding sulfide stress cracking ssc resistance is defined by ansi nace mr0175 iso 15156. Biaxial stress corrosion cracking frames capable of conducting testing in aggressive environments, such as brines with co 2 and h 2 s. You cant catch cracking in progress, the way you can catch metalremoval corrosion by monitoring thicknesses. Aug 14, 20 carneiro r a, ratnapuli r c and lins v f c l.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Sulphide stress cracking can be especially troublesome as. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. This part of iso 15156 addresses all mechanisms of cracking that can be caused by h2s, including sulfide stress cracking, stress corrosion cracking, hydrogen. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking.
The wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of khangirans sour gas wells. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Sulfide stress corrossion cracking resistant metallic materials for oil.
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